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Low rank or low-grade (LRC or LGC) coals are most abundant distribute around the several regions in the world. The contribution of low-rank coal is a significant role in the energy sectors and chemical feedstock to the industries. The hard coal reserves are gradually depleting, and the mining operation at deeper coal seam with greater difficulties as well as the cost of exploration is so high, which has a significant issue for plant economics. Therefore, the low-grade coal can be used as an alternative energy source to minimize these problems. Low-rank coals are usually associated with high mineral matter and moisture content, which exerts substantial impacts on their consumption including pyrolysis, liquefaction, gasification and combustion process. In order to understand the essential treatment of coal for efficient removal of mineral matters and improve coal properties by beneficiation techniques are crucial to developing advanced technologies. The present article provides a comprehensive overview of the various processes concerning demineralization of coal by chemical beneficiation technique. It has been found from the study; the degree of demineralization was greater in chemical beneficiation compared to physical beneficiation. It is because the chemical reagents are attacked to the interior of coal which removes the inorganic materials and finely dispersed minerals from the coal matrix. The chemical methods have separated all types of minerals from the coal matrix. However, the separation of minerals by the physical method depends on the mineral properties. Chemical beneficiation is an appropriate method to reduce both organic and inorganic mineral constituents from the LGC by leaching method. The chemical reagents are diffusing to the interior of coal matrix through the pores and subsequently dissolute the minerals. Throughout the study challenges, the chemical cleaning of low-grade coal has been efficient techniques for reducing the minerals to a minimum level that can be upgraded to high rank coal.
Beneficiation of coal fines with high ash content was attempted in an operating coal preparation plant by retrofitting a 0.5 m diameter pilot plant scale flotation column in the circuit. The collector and frother dosage were optimized as 0.680 kg/t and 0.058 kg/t respectively. At these reagent conditions the operating parameters of pilot scale flotation column were also optimized. The maximum yield of the froth obtained was 67.5% at the targeted ash level of 14% from a feed of 25% ash content. This was obtained at the operating parameters of 0.85 cm/s superficial air flow velocity, 0.57 cm/s superficial feed slurry velocity and 600 mm froth height. The performance of flotation column was found to be marginally better than that of the conventional flotation cells in the washery. Also, advantages such as low operational, maintenance and energy costs and operational flexibility in the case of flotation column could lead to financial accruals over a long run.
The nickeliferous iron ore of Hudenisht is located in the Pogradec area, Albania. It is developed in layers above
altered ophiolite and is covered by limestone of the Upper Cretaceous. The ore was characterized through XRD, ore
microscopy and SEM analysis and found that the main mineral phases are hematite, goethite and chromite, with chlorite (clinochlore, nimite), lizardite, calcite and spinel as minor phases. The main Ni-bearing phase is nimite, which appears mainly in the groundmass of the ore. The chemical analysis through XRF showed that it is a low-grade nickel ore (about 0.8% NiO) with Fe2O3 (74%) as the most abundant constituent. The ore was upgraded through physical beneficiation processes, namely gravimetric and magnetic separations. The received samples were homogenized, crushed to -8 mm and the product was sieved following the wet sieving procedure to obtain four size fractions, i.e. −8+4 mm, −4+1 mm, −1+0.250 mm and −0.250+0.063 mm. Each fraction was subjected to upgrading and the chemical analysis through XRF showed that the best results among the two processes were obtained through the gravimetric separation. It is observed that the float products are richer in nickel mainly in finer size fractions.
